📋 Tender Overview
Cement is one of the key materials for the safe storage of radioactive waste. What is needed is an almost infinite durability of the containers. Empa researchers are therefore analyzing material systems that can handle this task.When Barbara Lothenbach pushes ahead with her research projects she knows that she will not live to see the final result What she is working on should last between 100000 and one million years. The researcher from Empas Concrete Asphalt laboratory is investigating cement-based materials which are suitable for the disposal of radioactive waste. According to the Nuclear Energy Act deep geological repositories in Switzerland are to receive low- medium- and high-level nuclear waste in the future. For this purpose stable rock layers must be available to enclose the waste containers. Since materials scientists know however that no material is unchangeable a rock formation must be selected that is geologically as stable and dense as possible over thousands of years.The 180 million-year-old Opalinus Clay which extends in Switzerland between Olten and Schaffhausen at a depth of 600 meters for example has proven to be a suitable host rock. Since it has a low water conductivity it has excellent insulating properties. Rock solid sealed in the mountain But how do the crystalline structures and clay minerals of Opalinus Clay react with cement-based safety barriers when the gnawing ravages of time lead to changes The National Cooperative for the Disposal of Radioactive Waste Nagra requires data on this issue so that a final repository for nuclear waste can be embedded rock-solid in the Earth with regard to environmental protection and safety. Barbara Lothenbach and her team carry out the required analyses by conducting experiments under realistic conditions at the Mont Terri Rock Laboratory in St. Ursanne which was constructed in an Opalinus Clay layer.Together with international partners and research groups from Switzerland such as the University of Bern and the Paul Scherrer Institute PSI reactions of cement-based materials and the surrounding Opalinus Clay are simulated. The researchers are investigating and modeling the long-term development of the boundary layers between the very different material systems in experimental approaches lasting several years at different temperatures between 20 and 70 degrees Celsius. Comeback of an established acquaintance Of particular importance here is the strongly alkaline pH of cement which in conventional Portland cement can be as high as pH 13.5 or even higher. To ensure that the alkaline environment does not attack the clay minerals in the surrounding area a new development the so-called low-alkali cement seemed to be a good candidate for durable cement-based protective barriers. With a pH of 12.2 or lower it has an alkali concentration that is more than ten times lower. Lothenbach and her team therefore compared cement types with different pH values using thermodynamic modeling and X-ray diffraction analysis. This is the first time long-term results are available that allow the cement types and their evolution in the mountain to be characterized. It turned out that low-alkali cement is indeed more gentle on the clay minerals. However when conventional Portland cement is used chemical compounds are formed over time that lead to similarly favorable conditions in the safety barrier.As a result the cheaper and well-established Portland cement has once again become the focus of interest says Lothenbach. Intricate radioactivity Moreover if cement-based materials are to prevent radioactive substances from escaping into the environment under no circumstances must the reaction between the nuclear waste and the cement impair the safety barriers of the storage facility. Empa researchers have thus investigated radioactive isotopes present in the radioactive waste such as those of the element selenium in adsorption studies. The results show that selenium compounds are absorbed by the cement in large quantities. A protective barrier made of concrete delays the release of radioactivity into the biosphere since the cement minerals bind the radioactive substances and thus stop their spread concludes Lothenbach. However not all the processes taking place in the complex interplay of the materials that come into contact with each other can be evaluated so easily the researcher points out. She was hoping that the development of new low-alkali cements would offer advantages for the durability of the safety barriers. However the researchers discovered drawbacks in other properties Combining thermodynamic modeling and experimental data Lothenbachs team could see that such types of cement bind substances like radioactive iodide less well.Hazardous corrosion An insulation layer is desirable which is as waterproof as possible but not gas-tight. In a deep geological repository gases can be produced for example by corrosion of the enclosed steel containers whereby iron hydroxide is formed and hydrogen is released. Such gases which are produced in small quantities over time must be able to escape in order to prevent excess pressure from developing. In order to trace long-term reactions in the corrosion of iron at the boundary to the cement material the researchers carried out investigations using chemical analyses and spectroscopy. Initial results show that Portland cement with its high pH is more effective than low-alkali cement. More experiments are now planned to shed light on these still little-known corrosion processes. In addition Lothenbachs team has characterized the phases in the interaction zone of cement and Opalinus Clay that result from the interaction of clay minerals with the cements constituents such as a magnesium silicate phase. It has not yet been conclusively clarified that such intermediate layers are formed and could contribute to sealing the protective layer.
